Richard,
The method I use is to give the user you want to block a fixed IP address (you can fix his IP through the hostnames server panel - you'll need to know his MAC address), then deny web access to that IP in squid.conf. This involves modifying the templates and can get very messy if you are trying to block a large number of users. But for small numbers, it works.
By the way, this works both ways, ie. if you have a large number of people to block, specify to allow only the IPs you want and block all others. If you have a small number of people to block, do the reverse, ie. block the IPs you specify and allow all others through.
Kelvin