Hi Rob
Wow, someone actually reads my posts
If you do some research on Samba then you can find out how to modify the file samba.conf (i think, its been a while).
One of the settings in this file defines the role of the server when in an integrated domain; PDC or BDC (the SDC was a typo).
The problem with the default Samba setup is that it will work as a BDC as long as the PDC is up but as soon as it is down it will promote itself to the job without asking (as it assumes it is its role anyway - the original PDC is only preventing this from happening temporarily).
The users account/SAM sync happens automatically once the systems is a domain controller (within the update interval for the DC's sync); yes, the DC sync keeps all the accounts and p/w's in sync across all DC's.
HTH