There's no reason to assume consistency between the headers in the message and the envelope. The trivial example is the Bcc: header; more complex explanations might include email being forwarded from one account to another, or someone using the "Bounce" feature in their email client.
As a practical example, I received a copy of your message by email, and it was delivered to richl-forums@e-smith.com, but the To: header read
To: Experienced User Forum
The important debugging bits in the headers you posted in the original post
in this thread were the Delivered-To: headers, which told you what qmail
actually did with the message once it got it.
Cheers,
--Rich