You can have this feature if you patch the qmail source & recompile. The patch is available here:
http://js.hu/package/qmail/qmail-1.03-mfcheck.4.patchPersonally, I think it's a waste of time, but you did ask. Here's what the author says:
"It checks envelope sender (MAIL FROM: domain address) in DNS. Warning: it is not intended to filter out spammers, just a precaution not to accept mails from knowningly illegal addresses, and you'll get a lot less double bounce messages. Besides, it conforms with RFC 2821, section 3.6. Many thanks to Salvatore Toribio to help find a nasty bug around bounce checks."