Max,
The previous discussion dealt with ip-aliases using IPCop. To make the additions permenant, the statements would have to be added to rc.local (on IPCop).
With IPCop, DHCP did not work for the additional green network, but other services like routing, proxy and port forwarding did work.
It is likely this will work with SME, but you will only know if you test it on a test server.
ryan