Hint: DO NOT put a server in "Server Only" mode in a DMZ, that configuration is not secure.
Change it to "Server/Gateway" mode before connecting to a DMZ.
Depending on you exact configuration, you may need to disable SMTP transparent proxy to get it working properly.
/sbin/e-smith/config setprop smtpfront-qmail Proxy disabled
/sbin/e-smith/signal-event remoteaccess-update
But first, do a search on "SMTP transparent proxy" as this subject has been discussed many times.
Good Luck