Texasboy,
What is the content of the emails. If it is bounce notifications i.e fred@domain is not a user on this server then the chances are that some spammer is spoofing you email address.
If the content is actually spam then you either have a compromised email account that spammers are sending through or it is a machine on your network.
I made the unfortunate mistake once to set up a demo on my server and created a username and password of demo, demo. It didn't take the spammers long to access the account via SMTP-Auth and start sending spam through the account. Luckily I caught it after a couple of hours. If you have SMTP-Auth enabled on your server then check the CVM logs to see what accounts are logging on. Generally user@localhost entries are webmail.
I have also worked on a couple of PC's that were affected with a spam sending trojan. None of my AV scans would detect it. I only picked it up by looking at the processes running and stopping any that I was unsure of, until the spam stopped sending. Whatever you do, don't rely on Nortons to pick up trojans.
Jon