OK, without knowing the exact mechanics of how SME (or qmail) handles the e-mail internally, this suggestion is purely guesswork (hence the question mark at the end of my suggestion).
Case Study
In a previous setup, there was a SME server that needed to host a couple of virtual domains' web and mails but the primary domain's e-mails was to be handled by an internal Exchange server. We could not use the delegate mail server option as this delegates all mails not just the main domain's mails to the delegate server. Therefore, we used qmail's smtproute to route all mails bound for the main domain to the Exchange Server and kept all other virtual domains on the SME and this worked fine.
Noted that this is slightly different from Brenno's requirement's as he is aiming to redirect a Virtual domain's mails and not the main domain's mails. But as mentioned above, without knowing if SME (or qmail, or whichever component in the server) treats the main domain's mails differently to virtual domains' mails, it is reasonable to make the assumption that smtproutes might do the job in this situation as well and might be worth a shot (I thought in the Linux world, nothing ventured nothing gained ?).
Kelvin