This likely means that your ISP's mail server is not accepting mail from your IP address. Talk to them. Show the full bounce message here if you want confirmation that that is what the problem is.
I did not recieved this from gmail after trying to send via my server using smtp smarthost:
<xxxxxxxx@gmail.com>:
213.46.255.2 does not like recipient.
Remote host said: 550 5.1.1 <xxxxxxxx@gmail.com> recipient rejected 95.96.nn.nn is in RBL
Giving up on 213.46.255.2.
The named ip address is my internet connection's ip not the isp mailserver's ip.
Still wondering why the RBL takes my ip instead of my isp's ip to query for Rbl....
Geert