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Open ALL messages one by one in your email client eg Outlook, Thunderbird etc.
Look at the Properties or Headers of the message, different programs refer to it differently.
You can see all the mail servers the message passed through and the email addresses and aliases that the message was delivered to and then forwarded on to the final recipient address.
That should give you some clue.
Other than that carefully check all your users and groups settings to see if you have inadvertantly setup duplicate deliveries, eg a second sysadmin account that is receiving admin mail and then forwarding to yourself.
Other than that you may have problems with downloading messages eg if you use fetchmail, the mail server may not be identifying that the message has been delivered the first time and sends it again.
Other than that, check the various mail log files (View log files in server manager eg qpsmtpd, qmail etc), you should be able to track each message to see when and where it comes from.