That patch is to reduce, not increase, the number of emails to help reduce spam.
By default I'm not sure there really is a limit beyond physical capacity.
1.What errors do you get?
2. Why do you need to send that many? Use a group? Or use a proper newsletter/marketing mailing system like phplist.
I use phplist for newsletters and can send a lot in one go but usually rate limit it to reduce the chance of getting blocked as a spammer by remote hosts - which may be your users issue.
A lot of big providers will block you if you send too much too fast. Lets see the errors.