Hello,
I can take a stab at this since it is not really an E-smith question. I do not know the Cisco router specifically but there are couple of basic things.
1.) Do you get a link light when you plug the cables in? Generally a link light on the 3com card is a good sign. If you are having problems, you might have the wrong ethernet card plugged in. I was lucky when I setup my system that I picked the right card first.
2.) If you were to plug your Router into your Hub, do you need to plug into the "Uplink" port of the hub? If you do, chances are that you need a crossover cable. The Uplink port generally has the crossover built right into it so that you can use a normal cable.
See if any of this makes sense.