Expanding on Richard's comment, some bioses allow you to set a default that makes the PC power on when mains power is connected. Be aware that this can be dangerous for the system if mains power cuts in and out repeatedly. It is also possible to hack the ATX power connector and ground one pin to make the power supply switch on. I have used this method to test power supplies, but have not tried it on a working PC. Can't remember which pin on the connector, but will consult my notes and post again when I find out.
Regards
Pete.