This board works just fine with e-smith v.4.1.2, but there *MAY* be a problem with SME 5, which uses a completely non-standard kernel (non-standard vis-a-vis available drivers). Although SME5 is called RedHat 7.1, the RH7.1 drivers won't work, because RH7.1 actually uses kernel 2.4.2, while SME5 uses 2.2.19.
The Asus A7V should not be any part of the problem. You might have to get really fancy with SME5 (compile drivers from source and make your own install script) or install to a regular ide or scsi drive, then see if you can mount the 3ware card to hold the i-bays.
I once wrote a little how-to for adding raid controllers from Adaptec or Promise (online at the Mitel site) but these vendors do not publish source code, and none of their drivers are for 2.2.19 so my how-to won't work for SME5.