Hi Shaun...I've got a similar card (with a PDC20268 chip) waiting to go into my e-smith box. It *is* possible to get it working, after a fashion, but you won't be able to enable DMA xfers on any attached drives so you'll get crap performance out of it.
This is because the kernel shipped with 5.1.2 doesn't directly support the chipset on the Promise cards. The 2.4 kernel (included with RH7.3) has support compiled in out of the box (I've run a hacked e-smith with this kernel and performance was great) and will hopefully be a part of SME 5.2 when it comes out.
Hope that helps....
Gary