Jason,
The only thing i have seen that is even close to what you want is called 1-1NAT or 1-to-1 NAT. It allows you to add a second address, that point straight through to a single inside address.
Probably easier, as Boris said, to use a second box for this complicated firewall/router functionality and leave the SME unmodified and happy... but the 1-1NAT stuff might get you pointed in the right(wrong) direction.
Good luck.