It would seem you have a couple of realistic options to explore, and I am not sure configuring SME is a practical approach.
Option 1 would be to explore your server appication and see if it allows or can be configured to ban an IP. For instance, phpBB does have such a feature and is easily configured via the administrator panel.
Option 2 would be to configure your firewall appropriately, whether that is SME or some other device. I suppose you could use IPTables to accomplish this, but since you are asking how to do this, I am doubting you would know how to proceed on that path.
Banning of specific IP's for web site access is not a great way to prevent access. IP's are easily randomized, changed or otherwise spoofed. Any lamely talented mildly determined person could overcome that with a quick Google search.
...and I am not a big fan of being Boing'd....lol