First of all, the 4100 is not a modem. It is a modem/router combination with NAT built in. So in your first example you may actually have 2 routers if the 4100 is not bridged.
Is it set up in the default configuration (Router) or have you changed it to "Bridge Mode"?
Do you know your PPPoE username and password? If not, you may want to find out what they are before you go any further. If you have to reset the 4100, you may loose this information stored in the 4100.
You state that you have 2 dynamic IP's. If this is the case, I don't think that SME can use both (someone correct me here if I am mistaken) so you may need to leave the 4100 configured as a router and open the needed ports to the SME server or put the server in the DMZ.
Do you understand how to configure the 4100? It has a built-in web interface. Have you accessed the interface yet?
If you know how to use the interface, try the following.
1-Login and click Setup>Host. Take note of the host IP and Netmask settings. Let's say it is 10.0.0.1/255.255.255.0 for this example.
2-Click Setup>DHCP and disable this.
3-Click Setup>Firewall>DMZ and check "Enable DMZ with host IP address and put 10.0.0.2 in the box. Also check the radio button to make the setting permenent.
Now log into SME as admin and pick "2-Configure this server"
Step through and make sure you do the following.
1-Set the Internal IP to a different private address like 192.168.0.1.
2-Choose Server/Gateway (dedicated)
3-Choose Static IP and set the external interface to 10.0.0.2 (or whatever is set in the DMZ on the 4100).
Now connect the external interface of the SME to the LAN side of the 4100.
If you only need 1 of the IP addresses then I suggest that you "Bridge" the router and have SME connect directly to the internet but this will be an entirely different setup. Let me know if you want to try that instead. SME supports this but I don't know what it will do with 2 IP addresses. I assume it will just get assigned one IP.
By the way, I got all this info directly from the Siemens web site. If you don't have the manual you can download it from here
http://kb.efficient.com/utility/getfile.asp?rid=5226