Well, i'm a security guy and only want to allow access from one domain, so that i only have to make content filtering etc. regarding e-mail for this one domain.
Well content filtering works for all domains so you won't have to make different settings for each one.
Now for the zoneedit part....
Go to
http://www.zoneedit.com/ and signup (it's free).
Now login and add zones (you'll have to add dns of ZE at your domain registrar).
When you add their nameservers to your DNS records go back to
www.zonedit.com and click on domain name and then on web forwards.
Then you'll have to fill out subdomain (eg. mail) and under redirects to
http://server/webmail and click on cloaked so you'll see mail.domain.com instead of
http://server/webmail. Wait a few minutes and you're set.