In short, the windows machine (Win2k sp4) claims that my admin account is disabled/switched off when I try to log on to the domain for the first time after switchting from workgroup (dutch: werkgroep) to domain. After entering the admin/password combination, I get an error message
It's a little unclear if you are having problems with your windows client administrator accounts or the SME admin account.
Speaking in general terms, when you switched from a peer-to-peer (workgroup) network to domain network, you introduced another authentication layer to your setup. With a windows domain network, you have machine (or local) authentication and domain (or network) authentication. Whereas, with a peer-to-peer (workgroup) network, you are only dealing with the machine (local) authentication.
When you log into a windows domain you are granted certain network privileges and certain machine (local) privileges, based on the domain group(s) which you are a member of. The standard domain group Domain Admins is the group that is granted both domain administrator privileges and local machine administrator privileges.
Out-of-the-box, SME is configured so that the only SME user who is a member of the Domain Admins group is the SME "admin" user. You can change this by accessing the SME Groups server-manager panel and defining a group called something like "da" with the description "Domain Admins" This will map the SME group "da" to the domain group Domain Admins. Any SME users you add to the group "da" will be granted Domain Admin privileges when they log into the domain.
My guess is that you need to re-tool your thinking. With a domain network, you don't need local machine accounts. All authentication is done by SME. In fact, having local machine accounts can result in authentication conflicts if the same username is both a local username and a domain username (perhaps this is part of the issue you are having). Try removing all of the local machine accounts you had defined in your previous setup, create the user accounts in SME, then try logging in.