Now that is an interesting idea. I will try to dig into it, although I am not real deep in the BIOS stuff.
The old card is integrated on the motherboard. In this case, on Ethernet 1 is a 100/10 Mbps Realtek 8100B; on Ethernet 2 is a 100/10 Mbps Intel 562EZ.
I put a Netgear GA311 in the PCI slot today, and set SME to use it for the LAN port, just to see how things go. Still up some 4 hours after installation and measurably better throughput "inside" the gateway.
Of course, if it "disappears" tonight while I sleep, all bets on this solution are off.

In the meanwhile, since the XPC has only one PCI slot, I am considering an Intel PRO gigabit dual port server adapter to use instead.