...that way is when the user already login to the workstation and already have a profile. it's done with this way.
We need is - how to make Z:\My Documents since the first time the user login to the workstation. I think is not on windows side
I thought this was simple the way I did things. On each user once they are logged into WinXP, I right clicked on the my documents Icon on their desktop and selected properties. In the Target Tab, I clicked Move. Gave it the home directory drive set by the netlogon.bat ( I also have smeserver-logonscript installed). This moved all links to my documents to the new location. The only downside to this is if roaming profiles are turned on SME server. THis would then copy all the My Documents data from the SME network drive to the SME Samba User Profile storage. If you don't have roaming profiles turned on then Moving My Documents via the windows Target Button works well.