Note however that using TLS/SSL in the MTA isn't a silver bullet. You will have lots of disruption of mail delivery if you don't accept self-signed certs, but if you accept self-signed certs, then man-in-the-middle attacks become very simple, so your ISP (or somebody working with them) could crack open your email and read it.
If you care about secrecy of your email, do it end-to-end using PGP or S/MIME.