Thanks Charlie for the reply. I got the problem solved. First I did some research on the web at various MS/Win sites trying to find info on how to do this. I found nothing there. I dug a little deeper and found the answers I needed at the following site:
http://www.oreilly.com/catalog/netpc/excerpt/ch06-06.htmIt figures I would find the info at a site related to Linux/Unix

Heres what I did.
Step 1. Create a bat file and place the following commands in it based on your addressing needs of course.
route add 210.x.x.x 192.168.new.gateway
route add 208.x.x.x 192.168.esmith.address
The first command is adding the IP address I need to get to thru the new gateway.
The second command is adding the IP address of the DNS server my e-smith uses for ADSL internet connectivity.
Save the bat file anywhere you like and place a shortcut in Windows Startup thats is set to "run minimized" and "close on exit".
The reason for doing this is that Windows will only keep the route commands as longs as the system is on and will lose them once it is rebooted. You can type these in at a Dos prompt using the same syntax as the bat file for initial testing.
Step 2. Create a "hosts" file in C:windows that has the IP address of the site you need to get to thru the new gateway. In my case it was:
210.x.x.x blahblahnet
Save as hosts with no extension. Windows does us all a favor and hides the extensions by default so be sure to turn off that "feature".
Step 3. In network neighborhood properties on the tcp/ip properties for your network card be sure to have both gateways listed under "gateways".
Step 4. In the DNS section of the tcp/ip eyhernet properties in network neighborhood properties enable dns using the e-smith server for all the choices in the fields. Mine was already set that way before I tried this but when I tested on a client machine that had not been setup previously my access to the internet thru e-smith was unavailable until I added these settings. (oops!)
Well thats it, this worked for my customers network. Hope it helps someone in a similiar situation.