Despite the ADSL config, better check following first.
Possible your ISP blocked the 25 port and it is common in dynamic connection.
If above situration fit to your situ, go to server manager > Email setting> type in your ISP's smtp server name at ISP SMTP column.
If you sure it is not the ISP side config, check out the ADSL config with port forwarding of 25 to your linkage.
Hope it can help.