I gues one way of saying it is that you can not connect a e-smith to a pppoa connection, this will have to be done indirectly.
In my home I am using a Netopia router modem that I believe warks much the same way as the Netgear DG814 (that I only know from this link:
http://www.adslguide.org.uk/hardware/reviews/2002/q4/netgear-dg814.asp )
When you are installing a pppoa router modem (like my Netopia) in front of a e-smith ar an replacement for an pppoe connection what actually happen is that the pppoa modem/router takes over some of the functions that were performed by the e-smith before.
Using pppoe, the login can be performed from the PC. NAT fuctionality and firewalling is also performed by the e-smith PC.
Using PPPoA the login, the NAT fuctionality and the firewalling will (could) be performed by the PPPoA router modem.
Some and most older PPPoA modems work only in routing mode, that means that they just deliver an internal ip adresses to the network port inside. My Netopia modem is of that type. I believe that there is some newer PPPoA modems that also can work in bridging mode, which meen that they will deliver the external ip to the connected PC, the e-smith as an exsample.
So if you are using a PPPoA modem in routing mode an then a e-smith gatway at the inside of the PPPoA modem (that will also contain a router) you will actually have two router/firewalls connected in series.
If you on the other hand are using the PPPoA modem in a bridging mode things will be working more like "normal" for a PPPoE connection, I believe. (Except for that the logon will be from the modem itself.)
The way I use my PPPoA connection is as a modem/firewall/gateway and as an replacement for the e-smith in this role. Then I use the e-smith in server only mode at the LAN and at the inside of the PPPoA modem/gateway.
Just try to explain how I have experienced my "PPPoA problem". If I should be wrong, please note me !!
Some newer PPPoA modems has the option of operating in a routing/firewalling mode or a bridging mode. I don't know if the Netgear DG814 can do this. The article does not mention anything about this. The configuration excample that is in the article seems to use the olt type routing configuration. By the way my Netopia modem is now running very nice and without a problem, but it's command based configuration shell is rather terrible so I will not recomend it because of this. The web based interphase of the Netgear looks much bether. (But if I should buy a nw ppoa modem I would check if it can run in bridging mode as well.)